3 research outputs found
Marvel analysis of the measured high-resolution rovibrational spectra of H2S
44325 measured and assigned transitions of HS, the parent
isotopologue of the hydrogen sulfide molecule, are collated from 33
publications into a single database and reviewed critically. Based on this
information, rotation-vibration energy levels are determined for the ground
electronic state using the Measured Active Rotational-Vibrational Energy Levels
(MARVEL) technique. The ortho and para principal components of the measured
spectroscopic network of HS are considered separately. The verified
set of 25293 ortho- and 18778 para- HS transitions determine 3969
ortho and 3467 para energy levels. The Marvel results are compared with
alternative data compilations, including a theoretical variational linelist.Comment: 39 pages, 3 figures, JQSRT, 201
Marvel analysis of the measured high-resolution rovibrational spectra of H₂³²S
Abstract 44 325 measured and assigned transitions of H₂³²S, the parent isotopologue of the hydrogen sulfide molecule, are collated from 33 publications into a single database and reviewed critically. Based on this information, rotation-vibration energy levels are determined for the ground electronic state using the Measured Active Rotational-Vibrational Energy Levels (Marvel) technique. The ortho and para principal components of the measured spectroscopic network of H₂³²S are considered separately. The verified set of 25 293 ortho-- and 18 778 para- H₂³²S transitions determine 3969 ortho and 3467 para energy levels. The Marvel results are compared with alternative data compilations, including a theoretical variational linelist